| name | dangerous-goods-transport |
| description | Use when shipping hazardous or dangerous goods, classifying products by UN number or hazard class, choosing between air/sea/road/rail transport for a hazardous material, applying IATA DGR or IMDG Code or ADR or 49 CFR rules, determining packing group, completing a dangerous goods declaration, selecting hazmat labels and marks, shipping lithium batteries (UN 3480/3481/3090/3091), aerosols, flammables, corrosives, dry ice, or any substance regulated under the UN Orange Book modal regimes |
Dangerous Goods Transport
How to classify, document, pack, and declare dangerous goods for any transport mode. Scope: hazardous materials — classification, modal regimes, packing, marking, documentation. Boundary: customs-and-trade = duties and HS codes; import-export-docs = commercial paperwork; THIS skill = transport safety rules for hazardous materials.
MCP Tools
# Search for dangerous goods regulatory signals
mcp__claude_ai_Cleo_Insight__search_signals(q="dangerous goods", limit=25)
mcp__claude_ai_Cleo_Insight__search_signals(q="lithium battery transport", limit=25)
mcp__claude_ai_Cleo_Insight__search_signals(q="IATA dangerous goods", limit=25)
mcp__claude_ai_Cleo_Insight__search_signals(q="ADR dangerous goods road", limit=25)
# Get regulation details for DG frameworks
mcp__claude_ai_Cleo_Insight__get_regulation(id="<regulation-id>")
mcp__claude_ai_Cleo_Insight__list_regulations(limit=100)
Classification Decision Tree
digraph {
rankdir=TB; node [shape=box style=rounded fontsize=10];
start [label="Is the substance or article\nhazardous?" shape=diamond];
not_dg [label="Not dangerous goods.\nNo DG rules apply."];
class [label="Identify UN hazard class\n(1 through 9)"];
un_number [label="Look up UN number\nin Orange Book / modal tables"];
pg [label="Assign Packing Group\n(I = most dangerous,\nII = medium, III = least)"];
mode [label="Which transport\nmode(s)?" shape=diamond];
air [label="Air: IATA DGR\n(ICAO TI basis)\nStrictest limits"];
sea [label="Sea: IMDG Code\n(IMO)"];
road [label="Road EU: ADR\n(UNECE biennial)"];
rail [label="Rail: RID"];
us [label="US domestic: 49 CFR\n(HMR, PHMSA/DOT)"];
pi [label="Apply packing instruction\nfor that class + mode"];
label_mark [label="Apply hazmat labels\n(diamond) + marks\n(UN number, proper name)"];
decl [label="Complete Dangerous\nGoods Declaration\nfor that mode"];
train [label="Shipper trained?\n(IATA cat 6 / ADR 1.3?)" shape=diamond];
ok [label="Ready to ship"];
train_req [label="Training required\nbefore tendering"];
start -> not_dg [label="NO"];
start -> class [label="YES"];
class -> un_number -> pg -> mode;
mode -> air [label="Air"];
mode -> sea [label="Sea"];
mode -> road [label="Road EU"];
mode -> rail [label="Rail"];
mode -> us [label="US domestic"];
air -> pi; sea -> pi; road -> pi; rail -> pi; us -> pi;
pi -> label_mark -> decl -> train;
train -> ok [label="YES"];
train -> train_req [label="NO"];
}
The 9 UN Hazard Classes
| Class | Name | Sub-divisions | Examples | Packing Group |
|---|
| 1 | Explosives | 1.1–1.6 (mass explosion → minor hazard) | Fireworks, airbag inflators (UN 0503), signal flares | N/A (compatibility groups A–S) |
| 2 | Gases | 2.1 Flammable, 2.2 Non-flammable, 2.3 Toxic | Aerosols (UN 1950 Class 2.1), propane, oxygen cylinders, CO₂ | None (pressure drives limits) |
| 3 | Flammable liquids | — | Perfume/cologne (UN 1266), nail polish (UN 1263), ethanol (UN 1170), essential oils | I / II / III by flash point |
| 4 | Flammable solids / Spontaneous combustion / Water-reactive | 4.1 / 4.2 / 4.3 | Matches (UN 1944/2254), metal powders, sodium (UN 1428) | I / II / III |
| 5 | Oxidizers / Organic peroxides | 5.1 Oxidizers, 5.2 Organic peroxides | Hydrogen peroxide >8% (UN 2014), benzoyl peroxide (UN 3104) | I / II / III |
| 6 | Toxic / Infectious | 6.1 Toxic, 6.2 Infectious | Pesticides, UN 2814 (Category A infectious), UN 3373 (diagnostic specimens) | I / II / III |
| 7 | Radioactive | — | Medical radioisotopes, uranium ore; requires RAM certification | N/A (categories I/II/III/fissile) |
| 8 | Corrosives | — | Lead-acid batteries (UN 2794), hydrochloric acid (UN 1789), sodium hydroxide (UN 1824) | I / II / III |
| 9 | Miscellaneous | — | Lithium-ion batteries (UN 3480/3481), lithium-metal batteries (UN 3090/3091), dry ice (UN 1845), environmentally hazardous substances (UN 3082/3077), magnetized material | I / II / III or none |
Modal Regimes
| Mode | Regulation | Authority | Update Cadence | Key Feature |
|---|
| Air | IATA Dangerous Goods Regulations (DGR), based on ICAO Technical Instructions (Annex 18 + Doc 9284) | IATA + ICAO | Annual (IATA DGR edition) | Most restrictive; many forbidden items; quantity per package caps lower than sea/road |
| Sea | IMDG Code (International Maritime Dangerous Goods Code) | IMO | Biennial (even years) | Stowage + segregation between classes; segregation table mandatory |
| Road — EU / international | ADR (European Agreement concerning the International Carriage of Dangerous Goods by Road) | UNECE | Biennial (odd years) | Tunnel restrictions; driver ADR certificate; transport document required |
| Rail — EU / international | RID (Regulations concerning the International Carriage of Dangerous Goods by Rail) | OTIF (appendix C to COTIF) | Biennial (aligned with ADR) | Annexed to CIM consignment note |
| Inland waterways | ADN (European Agreement for Inland Waterways) | UNECE | Biennial | Vessel certificate required |
| US domestic | 49 CFR Parts 171–180 — Hazardous Materials Regulations (HMR) | PHMSA / DOT | Continuous (Federal Register) | Applies to all US carriers; different proper shipping names and packing instructions from IATA/IMDG for some items |
| Source of all | UN Recommendations on the Transport of Dangerous Goods — Model Regulations ("Orange Book"); UN Manual of Tests and Criteria (tests, incl. UN 38.3 for lithium) | UNECE TDG Committee | Biennial | All modal rules derive from and align with the Orange Book |
Lithium Battery Reference
| Parameter | Li-ion cells/batteries alone | Li-ion in / with equipment | Li-metal cells/batteries alone | Li-metal in / with equipment |
|---|
| UN number | UN 3480 | UN 3481 | UN 3090 | UN 3091 |
| Hazard class | 9 | 9 | 9 | 9 |
| UN 38.3 test | Required for every cell/battery design | Required | Required | Required |
| State of charge (air) | Cells and batteries shipped alone: ≤ 30% of rated capacity | N/A (in/with equipment: full SoC permitted) | ≤ not capped at 30%; follow IATA DGR section requirements | N/A |
| Packing instruction split | Section II (small) vs Section IA / IB (large) — threshold by watt-hour rating of the battery | Section II vs IA/IB by Wh | Section II (small) vs Section IA/IB by lithium content (g) | Section II vs IA/IB |
| Air quantity limit (Section II) | Per-package Wh limit; check current IATA DGR edition for exact figure | Quantity of equipment drives limit | Per-package lithium content limit (g); check current IATA DGR | Quantity limit per package |
| Forbidden on passenger aircraft | Section IA (large): cargo aircraft only | Section IA (large): cargo aircraft only | Section IA (large): cargo aircraft only | Section IA (large): cargo aircraft only |
| Label | Class 9 diamond + lithium battery handling mark | Class 9 diamond + lithium battery handling mark | Class 9 diamond + lithium battery handling mark | Class 9 diamond + lithium battery handling mark |
| Section II mark | Lithium battery mark (UN 3480) + UN number + emergency phone | Same + UN 3481 | Lithium battery mark (UN 3090) | Same + UN 3091 |
Note on watt-hour thresholds: IATA DGR revises exact Wh cut-offs in each annual edition. Verify against the current edition rather than relying on a prior-year figure. For Section II eligibility in the edition in force, check Table 9.3.A (ion) and 9.3.B (metal).
Marks and Labels Summary
| Requirement | Description | Applies To |
|---|
| Hazard label (diamond) | Class-specific diamond, minimum 100mm × 100mm (international); 4-inch × 4-inch (US) | All DG packages; outer packaging |
| UN number mark | "UN" + 4-digit number (e.g., UN 3480) on package | All DG packages |
| Proper shipping name | Full technical name from modal tables (e.g., "Lithium ion batteries") | All DG packages |
| Packing group | Indicated on mark where applicable (e.g., "PG II") | Classes 3, 4, 5, 6.1, 8, some 9 |
| Orientation arrows | Two upward-pointing arrows for liquid-containing packages | Packages with liquids, cryogenics |
| Overpack mark | "OVERPACK" on outer container + all inner marks visible or listed | Overpacks containing DG |
| Lithium battery handling mark | Specific IATA/ICAO mark showing battery + warning text | All lithium battery shipments |
| Marine pollutant mark | Dead fish + tree triangle | Environmentally hazardous substances (UN 3082, UN 3077) by sea |
| Limited quantity (LQ) mark | White diamond with black border + "Y" or mass | LQ shipments (reduced requirements, air and sea) |
| Excepted quantity (EQ) mark | White with inner diamond per class colour | Excepted quantities (very small amounts) |
| UN certification mark | Printed on UN-specification packaging (e.g., "UN 4G/Y10/S/…") | All DG packaging must bear UN performance test mark |
Dangerous Goods Declaration Template
DANGEROUS GOODS DECLARATION -- [Shipment Reference] -- [Date]
Shipper: [Company name, address, country]
Consignee: [Company name, address, country]
Transport mode: [ ] AIR [ ] SEA [ ] ROAD [ ] RAIL
TWO-LETTER IATA AIRPORT CODES (air): Origin: ___ Destination: ___
Vessel / Voyage (sea): ___________________________
Vehicle plate (road): ___________________________
-------------------------------------------------------------------
| Field | Entry |
-------------------------------------------------------------------
| Proper shipping name | [e.g., Lithium ion batteries] |
| UN number | [e.g., UN 3480] |
| Class / division | [e.g., 9] |
| Subsidiary risk | [if any, e.g., 8] |
| Packing group | [I / II / III / N/A] |
| Packing instruction | [e.g., PI 965 Section II (IATA)] |
| Quantity and type of packs| [e.g., 4 cartons, 2 batteries each]|
| Net quantity per package | [e.g., 160 Wh per battery] |
| Total net quantity | [e.g., 1.28 kWh / 1,280 g] |
| Packaging specification | [UN 4G/Y10/S or outer box spec] |
| State of charge (Li only) | [e.g., ≤30% SoC for air] |
| UN 38.3 test reference | [Test summary report reference] |
-------------------------------------------------------------------
Additional handling information:
[e.g., "Keep away from heat. Do not short-circuit. Cargo aircraft only."]
Emergency response telephone: [24h number]
Declaration:
"I hereby declare that the contents of this consignment are fully and accurately described
